Q:

Can I access Windows Kernel system calls directly?

I have been doing research into Windows internals, and have just recently learned about system calls and I am wondering if it is possible to use these system calls like functions? I understand they aren't really meant to be accessed externally.
For instance: NtUserEmptyClipboard is a system call in Win32k.sys, and it's address is 0x117f
If I wanted to use this call like a function, how could I do so?

A:

What you want to do depends heavily on the architecture you're interested, but the thing to know is, that ntdll.dll is the user-mode trampoline for every syscall - i.e. the only one who actually makes syscalls at the end of the day is ntdll.
So, let's disassemble one of these methods in WinDbg, by opening up any old exe (I picked notepad). First, use x ntdll!* to find the symbols exported by ntdll:
0:000> x ntdll!*
00007ff9`ed1aec20 ntdll!RtlpMuiRegCreateLanguageList (void)
00007ff9`ed1cf194 ntdll!EtwDeliverDataBlock (void)
00007ff9`ed20fed0 ntdll!shortsort_s (void)
00007ff9`ed22abbf ntdll!RtlUnicodeStringToOemString$fin$0 (void)
00007ff9`ed1e9af0 ntdll!LdrpAllocateDataTableEntry (void)
...

So, let's pick one at random, NtReadFile looks neato. Let's disassemble it:
0:000> uf ntdll!NtReadFile

ntdll!NtReadFile:
00007ff9`ed21abe0 4c8bd1          mov     r10,rcx
00007ff9`ed21abe3 b805000000      mov     eax,5
00007ff9`ed21abe8 0f05            syscall
00007ff9`ed21abea c3              ret

Here, we see that we stuff away rcx, put the syscall number into eax, then call the syscall instruction. Every syscall has a number that is assigned arbitrarily by Windows (i.e. this number is a secret handshake between ntdll and the kernel, and changes whenever Microsoft wants)
None of these instructions are "magic", you could execute them in your app directly too (but there's no practical reason to do so, of course - just for funsies)

